Superconductivity in Nax_xCoO2_2⋅\cdotyH2_2O : Is Spin-Charge Separation Protecting a d1_1+id2_2 State ?

preprint2003arXivOpen access

Abstract

Superconductivity in Nax_xCoO2_2⋅\cdotyH2_2O is likely to be a p or d-wave; however, experiments are unable to pinpoint the symmetry. A simple estimate of pair breaking effects from an unavoidable `Na+^+ vacancy disorder' in an ordered Na+^+ lattice, at an optimal xopt≈0.30x_{\rm opt} \approx 0.30 is shown to destroy a Fermi liquid based p or d-wave superconductivity. However, a robustness of superconducting and normal states, seen in experiments is pointed out and argued to imply presence of a `quantum protectorate', possibly a `spin-charge decoupling' that protects a d1_1+id2_2 and not a p-state. A calculation of Knight shift and 1T1{1\over T_1} in the framework of RVB mean field theory and a fit to the data of Kobayashi etal.{\it et al.} [9] is made.

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