Abstract

We report the superconducting properties of single crystals of the intermetallic perovskite-related compound BaBi3_{3}. The superconducting transition temperature (Tc=5.82T_{c}=5.82~K) was obtained from heat capacity measurements. Using the measured values for the critical fields Hc1,Hc2H_{c1}, H_{c2}, and the specific heat CC, we estimate the thermodynamic critical field HcH_{c}(0), coherence length ξξ(0), Debye temperature ΘDΘ_{D} and coupling constant λepλ_{ep}. ΔC/γTcΔC/γT_{c} and λepλ_{ep} suggest that BaBi3_{3} is a moderately coupled superconductor and γγ suggests an enhanced density of states at the Fermi level. Electronic band structure calculations show a complex Fermi surface and a moderately high DOS at the Fermi level. Further analysis of the electronic specific heat shows that the superconducting properties are dominated by s-wave gap.

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