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Superconducting and thermoelectric properties of new layered Superconductor Bi4O4S3

Polycrystalline sample of the new layered superconductor Bi4O4S3 is successfully synthesized by solid-state reaction method by using Bi, S and Bi2O3 powders with one step reaction. The superconducting transition temperature (Tconset=4.5 K), the zero resistance transition temperature (Tc0=4.07 K) and the diamagnetic transition temperature (4.02 K at H=10 Oe) were confirmed by electrical transport and magnetic measurements. Also, our results indicate a typical type II-superconductor behavior. In addition, a large thermoelectric effect was observed with a dimensionless thermoelectric figure of merit (ZT) of about 0.03 at 300K, indicating Bi4O4S3 can be a potential thermoelectric material.

preprint2012arXivOpen access
S. G. TanL. J. LiY. LiuP. TongB. C. ZhaoW. J. LuY. P. Sun
cond-mat.supr-concond-mat.mtrl-sci
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S. G. TanL. J. LiY. LiuP. TongB. C. ZhaoW. J. LuY. P. Sun

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