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Study of grain boundary transparency in (Yb1-xCax)Ba2Cu3O bi-crystal thin films over a wide temperature, field and field orientation range

The residual low angle grain boundary (GB) network is still the most important current-limiting mechanism operating in bi-axially textured rare earth barium copper oxide (REBCO) coated conductors. While Ca-doping is well established to improve super-current flow across low angle GBs in weak fields at high temperatures, Ca-doping also depresses Tc, making it so far impractical for high temperature applications of REBCO coated conductors. On the other hand, high field magnet applications of REBCO require low temperatures. Here we systematically evaluate the effectiveness of Ca-doping in improving the GB transparency, r$^{GB}$= Jc$^{GB}$/Jc$^{grain}$ , of low angle Yb1-xCaxBaCuO [001] tilt bi-crystal films down to 10K and with magnetic fields perpendicular and parallel to the film surfaces, while varying the Ca and oxygen doping level. Using Low Temperature Scanning Laser Microscopy (LTSLM) and Magneto-Optical Imaging (MOI), we found rGB to strongly depend on the angle between magnetic field and the GB plane and clearly identified regimes in which Jc$^{GB}$ can exceed Jc$^{grain}$ (r$^{GB}$>1) where the GB pinning is optimized by the field being parallel to the GB dislocations. However, even in this favorable situation, we found that r$^{GB}$ became much smaller at lower temperatures. Calculations of the GB Ca segregation profile predict that the high Jc channels between the GB dislocation cores are almost Ca-free. It may be therefore that the positive effects of Ca doping seen by many authors near Tc are partly a consequence of the higher Tc of these Ca-free channels.