Structure and magnetism in nanocrystalline Ca(La)B6_6 films

preprint2004arXivOpen access

Abstract

Nanocrystalline films of La-doped CaB6_6 have been fabricated by using a rf-magnetron sputtering. Lattice expansion of up to 6% with respect to the bulk value was observed along the direction perpendicular to the film plane, which arises from the trapping of Ar gas into the film. Large ferromagnetic moment of 3 ~ 4 Bohr magneton per La has been observed in some La-doped films only when the lattice expansion rate is larger than 2.5%.

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