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Structural and magnetic properties of a new and ordered quaternary alloy MnNiCuSb (SG: F-43m)

We have synthesized a new crystallographically ordered quaternary Heusler alloy, MnNiCuSb. The crystal structure of the alloy has been determined by Rietveld refinement of the powder x-ray diffraction data. This alloy crystallizes in the LiMgPdSb type structure with F-43m space group. MnNiCuSb is a ferromagnet with a high TC ~ 690K and magnetic moment of 3.85MuB/f.u. Besides this we have also studied two other off-stoichiometric compositions; one Cu rich and the other Ni rich (MnNi0.9Cu1.1Sb and MnNi1.1Cu0.9Sb) which are also ferromagnets. It must be stressed that MnNiCuSb is one of the very few known, non-Fe containing quaternary Heusler alloys with 1: 1: 1: 1 composition.

preprint2015arXivOpen access
Zeba HaqueGohil S. ThakurSomnath GharaL. C. GuptaA. SundaresanA. K. Ganguli
cond-mat.mtrl-sci
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Zeba HaqueGohil S. ThakurSomnath GharaL. C. GuptaA. SundaresanA. K. Ganguli

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