Abstract
We study topological phase transitions in tetragonal NaZnSbBi, driven by the chemical composition . Notably, we examine mirror Chern numbers that change without symmetry indicators. First-principles calculations are performed to show that NaZnSbBi experiences consecutive topological phase transitions, diagnosed by the strong topological index and two mirror Chern numbers and . As the chemical composition increases, the topological invariants () change from , , , to at = 0.15, 0.20, and 0.53, respectively. A simplified low-energy effective model is developed to examine the mirror Chern number changes, highlighting the central role of spectator Dirac fermions in avoiding symmetry indicators. Our findings suggest that NaZnSbBi can be an exciting testbed for the exploration of the interplay between the topology and symmetry.
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