Abstract

New laboratory data of ethyl mercaptan, CH3_{3}CH2_{2}SH, in the millimeter and submillimeter-wave domains (up to 880 GHz) provided very precise values of the spectroscopic constants that allowed the detection of gauchegauche-CH3_3CH2_2SH towards Orion KL. 77 unblended or slightly blended lines plus no missing transitions in the range 80-280 GHz support this identification. A detection of methyl mercaptan, CH3_{3}SH, in the spectral survey of Orion KL is reported as well. Our column density results indicate that methyl mercaptan is ≃\simeq 5 times more abundant than ethyl mercaptan in the hot core of Orion KL.

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