Spectral functions in doped transition metal oxides

preprint1996arXivOpen access

Abstract

We present experimental photoemission and inverse photoemission spectra of SrTiO3−δ_{3- δ} representing electron doped d0d^0 systems. Photoemission spectra in presence of electron doping exhibit prominent features arising from electron correlation effects, while the inverse photoemssion spectra are dominated by spectral features explainable within single-particle approaches. We show that such a spectral evolution in chemically doped correlated systems is not compatible with expectations based on Hubbard or any other similar model. We present a new theoretical approach taking into account the inhomogeneity of the `real' system which gives qualitatively different results compared to standard `homogeneous' models and is in quantitative agreement with experiments.

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