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Spatially resolved observations of Europa's surface with Subaru/IRCS at 1.0-1.8 $μm$: Upper limits to the abundances of hydrated Cl-bearing salts

Recent infrared observations at 1.5-4.0 $μm$ using large ground-based telescopes have suggested that Cl-bearing salts are likely present on Europa's surface as non-ice materials. The chemical compositions of those Cl-bearing salts are key to understanding Europa's ocean chemistry and habitability. Here we report the results of ground-based telescope observations of Europa across two wavelength ranges, 1.0-1.5 and 1.5-1.8 $μm$, of which the former range includes absorption features owing to some hydrated Cl-bearing salts. We obtained spatially resolved reflectance spectra using the Subaru Telescope/IRCS and the adaptive optics system AO188 with high wavelength resolutions ($δλ$ ~ 2 nm for 1.0-1.5 $μm$ and $δλ$ ~ 0.9 nm for 1.5-1.8 $μm$) and low noise levels (1$σ$ ~ 1-2 $\times$ 10$^{-3}$). We found no clear absorption features at ~1.2 $μ$m caused by hydrated Cl-bearing salts. We estimated that conservative upper limits to the abundances of MgCl$_2$$\cdot$nH$_2$O, NaClO$_4$$\cdot$2H$_2$O, Mg(ClO$_3$)$_2$$\cdot$6H$_2$O, and Mg(ClO$_4$)$_2$$\cdot$6H$_2$O on Europa are 17% (<10% for most) at the 3$σ$ noise level. These values are lower than the proposed abundance of some hydrated Cl-bearing salts (> ~20%) on Europa based on previous observations. This supports the idea that Cl-bearing salts on Europa are likely anhydrous Na salts of NaCl and/or NaClO$_4$, or hydrated NaCl$\cdot$2H$_2$O. The presence of Na salts suggests that Na$^+$ could be the major cation in Europa's ocean, which would be possible if the oceanic pH is circumneutral or alkaline.