Single-Ion Atomic Clock with 3×10−183\times10^{-18} Systematic Uncertainty

preprint2016arXivOpen access

Abstract

We experimentally investigate an optical frequency standard based on the 2S1/2(F=0)→2F7/2(F=3)^2S_{1/2} (F=0)\to {}^2F_{7/2} (F=3) electric octupole (\textit{E}3) transition of a single trapped 171^{171}Yb+^+ ion. For the spectroscopy of this strongly forbidden transition, we utilize a Ramsey-type excitation scheme that provides immunity to probe-induced frequency shifts. The cancellation of these shifts is controlled by interleaved single-pulse Rabi spectroscopy which reduces the related relative frequency uncertainty to 1.1×10−181.1\times 10^{-18}. To determine the frequency shift due to thermal radiation emitted by the ion's environment, we measure the static scalar differential polarizability of the \textit{E}3 transition as 0.888(16)×10−400.888(16)\times 10^{-40} J m2^2/V2^2 and a dynamic correction η(300 K)=−0.0015(7)η(300~\text{K})=-0.0015(7). This reduces the uncertainty due to thermal radiation to 1.8×10−181.8\times 10^{-18}. The residual motion of the ion yields the largest contribution (2.1×10−18)(2.1\times 10^{-18}) to the total systematic relative uncertainty of the clock of 3.2×10−183.2\times 10^{-18}.

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