Sieving hydrogen based on its high compressibility

preprint2010arXivOpen access

Abstract

A molecular sieve for hydrogen is presented based on a carbon nanotube intramolecular junction and a C60C_{60}. The small interspace formed between C60C_{60} and junction provides a size changeable channel for the permselectivity of hydrogen while blocking NeNe and ArAr. The sieving mechanism is due to the high compressibility of hydrogen.

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