Shifted Tietz-Wei oscillator for simulating the atomic interaction in diatomic molecules

preprint2015arXivOpen access

Abstract

The shifted Tietz-Wei (sTW) oscillator is as good as traditional Morse potential in simulating the atomic interaction in diatomic molecules. By using the Pekeris-type approximation to deal with the centrifugal term, we obtain the bound-state solutions of the radial Schrödinger equation with this typical molecular model via the exact quantization rule (EQR). The energy spectrum for a set of diatomic molecules (NO(a4Πi)NO \left(a^4Π_i\right), NO(B2Πr)NO \left(B^2Π_r\right), NO(L′2ϕ)NO \left(L'^2ϕ\right), NO(b4Σ−)NO \left(b^4Σ^{-}\right), ICl(X1Σg+)ICl\left(X^1Σ_g^{+}\right), ICl(A3Π1)ICl\left(A^3Π_1\right) and ICl(A′3Π2)ICl\left(A'^3Π_2\right) for arbitrary values of nn and ℓ\ell quantum numbers are obtained. For the sake of completeness, we study the corresponding wavefunctions using the formula method.

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