Shear banding of colloidal glasses - a dynamic first order transition?

We demonstrate that application of an increasing shear field on a glass leads to an intriguing dynamic first order transition in analogy to equilibrium transitions. By following the particle dynamics as a function of the driving field in a colloidal glass, we identify a critical shear rate upon which the diffusion time scale of the glass exhibits a sudden discontinuity. Using a new dynamic order parameter, we show that this discontinuity is analogous to a first order transition, in which the applied stress acts as the conjugate field on the system's dynamic evolution. These results offer new perspectives to comprehend the generic shear banding instability of a wide range of amorphous materials.

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