Self-diffusion of a sphere in an effective medium of rods

preprint2009arXivOpen access

Abstract

Self-diffusion of a sphere in a network of rods is analyzed theoretically. Hydrodynamic interactions are taken into account according to the model of Dhont et al., under the assumption that $\ka << 1$ and aˉ/L<<1\bar{a}/L<<1, where 1/κ1/κ is the network hydrodynamic screening length, aˉ=a+D/2\bar{a}=a+D/2, and aa is the sphere radius, while DD and LL are the diameter and length of a rod, respectively. Simple expressions for the diffusion coefficients are derived and shown to be independent of LL.

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