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Paper detail

Selective surface functionalization at regions of high local curvature in graphene

Monolayer graphene was deposited on a Si wafer substrate decorated with SiO2 nanoparticles (NPs) and then exposed to aryl radicals that were generated in situ from their diazonium precursors. Using micro-Raman mapping, the aryl radicals were found to selectively react with the regions of graphene that covered the NPs. The enhanced chemical reactivity was attributed to the increased strain energy induced by the local mechanical deformation of the graphene.

preprint2012arXivOpen access
Q. WuY. WuY. HaoJ. GengM. CharltonS. ChenY. RenH. JiH. LiD. W. BoukhvalovR. D. PinerC. W. BielawskiR. S. Ruoff
cond-mat.mes-hallcond-mat.mtrl-sciphysics.chem-ph
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Open access13 authors3 topics
Imported metadata coverageMissing code, dataset, citation and institution fields are tracked without dominating the paper.Details
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Q. WuY. WuY. HaoJ. GengM. CharltonS. ChenY. RenH. JiH. LiD. W. BoukhvalovR. D. PinerC. W. BielawskiR. S. Ruoff

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