Paper detail

Rotational spectroscopy of isotopic vinyl cyanide, H$_2$C=CH$-$C$\equiv$N, in the laboratory and in space

The rotational spectra of singly substituted $^{13}$C and $^{15}$N isotopic species of vinyl cyanide have been studied in natural abundances between 64 and 351 GHz. In combination with previous results, greatly improved spectroscopic parameters have been obtained which in turn helped to identify transitions of the $^{13}$C species for the first time in space through a molecular line survey of the extremely line-rich interstellar source Sagittarius B2(N) in the 3 mm region with some additional observations at 2 mm. The $^{13}$C species are detected in two compact ($\sim 2.3''$), hot (170 K) cores with a column density of $\sim 3.8 \times 10^{16}$ and $1.1 \times 10^{16}$ cm$^{-2}$, respectively. In the main source, the so-called ``Large Molecule Heimat'', we derive an abundance of $2.9 \times 10^{-9}$ for each $^{13}$C species relative to H$_2$. An isotopic ratio $^{12}$C/$^{13}$C of 21 has been measured. Based on a comparison to the column densities measured for the $^{13}$C species of ethyl cyanide also detected in this survey, it is suggested that the two hot cores of Sgr B2(N) are in different evolutionary stages. Supplementary laboratory data for the main isotopic species recorded between 92 and 342 GHz permitted an improvement of its spectroscopic parameters as well.

preprint2008arXivOpen access

Signal facts

What is known right now

Open access5 authors1 topic

Next steps

Decide what to do with this paper

Use like or dislike for the fast social read. The more specific scholarly feedback stays available below when needed.

Log in to curate

Reading frame

Keep the important context close to the paper

Keep the important signals around this paper in one place: votes, save state, collection context, reviews and the metadata you need before deciding what to do next.

Institutions

Add specific reaction

Move through the context

Research map

Open full explorer

Move through nearby people, institutions, topics and adjacent work without leaving the paper page.

Building this map preview

BZPEER is loading the nearby papers, people, topics and institutions for this page.

Structured reviews

0 review(s)

ContributeLeave structured feedbackUse the review template when you have a concrete strength, concern or method question.Open review form

No structured reviews yet. High-signal critique starts here.

Work discussion

0 comment(s)

DiscussAdd a high-signal commentKeep quick notes, caveats and replication pointers separate from formal reviews.Open comment form

No discussion yet. The first strong comment sets the tone.