Rotational spectroscopy of isotopic oxirane, $c$-C$_2$H$_4$O

We studied the rotational spectrum of oxirane in a sample of natural isotopic composition in selected regions between 158 GHz and 1093 GHz. Investigations of the isotopologs with one $^{13}$C or one $^{18}$O were the primary focus in order to facilitate searches for them in space. We also examined the main isotopic species mainly to look into the performance of Watson's A and S reductions both in an oblate and in a prolate representation. Even though oxirane is a rather asymmetric oblate rotor, the A reduction in the III$^l$ representation did not yield a satisfactory fit, as was observed frequently earlier for other molecules. The other three combinations yielded satisfactory fits of similar quality among each other; the A reduction in the I$^r$ representation required two parameters less than both S reduction fits.

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