Retardation and flow at the glass transition

The crossover from back-and-forth jumps between structural minima to the no-return jumps of the viscous flow is modeled in terms of an ensemble of double-well potentials with a finite decay probability. The ensemble is characterized by the Kohlrausch-exponent $β$ of the time dependence $t^β$ of the response at short times. The model is applied to shear and dielectric data from the literature.

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