Recurrence and differential relations for spherical spinors

preprint2010arXivOpen access

Abstract

We present a comprehensive table of recurrence and differential relations obeyed by spin one-half spherical spinors (spinor spherical harmonics) Ωκμ(n)Ω_{κμ}(\mathbf{n}) used in relativistic atomic, molecular, and solid state physics, as well as in relativistic quantum chemistry. First, we list finite expansions in the spherical spinor basis of the expressions A⋅B Ωκμ(n)\mathbf{A}\cdot\mathbf{B}\,Ω_{κμ}(\mathbf{n}) and {A⋅(B×C) Ωκμ(n)\mathbf{A}\cdot(\mathbf{B}\times\mathbf{C})\, Ω_{κμ}(\mathbf{n})}, where A\mathbf{A}, B\mathbf{B}, and C\mathbf{C} are either of the following vectors or vector operators: n=r/r\mathbf{n}=\mathbf{r}/r (the radial unit vector), e0\mathbf{e}_{0}, e±1\mathbf{e}_{\pm1} (the spherical, or cyclic, versors), σ\boldsymbolσ (the 2×22\times2 Pauli matrix vector), L^=−ir×∇I\hat{\mathbf{L}}=-i\mathbf{r}\times\boldsymbol{\nabla}I (the dimensionless orbital angular momentum operator; II is the 2×22\times2 unit matrix), J^=L^+1/2σ\hat{\mathbf{J}}=\hat{\mathbf{L}}+1/2\boldsymbolσ (the dimensionless total angular momentum operator). Then, we list finite expansions in the spherical spinor basis of the expressions A⋅B F(r)Ωκμ(n)\mathbf{A}\cdot\mathbf{B}\,F(r)Ω_{κμ}(\mathbf{n}) and A⋅(B×C) F(r)Ωκμ(n)\mathbf{A}\cdot(\mathbf{B}\times\mathbf{C})\, F(r)Ω_{κμ}(\mathbf{n}), where at least one of the objects A\mathbf{A}, B\mathbf{B}, C\mathbf{C} is the nabla operator ∇\boldsymbol{\nabla}, while the remaining ones are chosen from the set n\mathbf{n}, e0\mathbf{e}_{0}, e±1\mathbf{e}_{\pm1}, σ\boldsymbolσ, L^\hat{\mathbf{L}}, J^\hat{\mathbf{J}}.

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