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Quantum Boltzmann equation for spin-dependent reactions in the kinetic regime

We derive and analyze an effective quantum Boltzmann equation in the kinetic regime for the interactions of four distinguishable types of fermionic spin-$\frac{1}{2}$ particles, starting from a general quantum field Hamiltonian. Each particle type is described by a time-dependent, $2 \times 2$ spin-density ("Wigner") matrix. We show that density and energy conservation laws as well as the H-theorem hold, and enumerate additional conservation laws depending on the interaction. The conserved quantities characterize the $t \to \infty$ thermal (Fermi-Dirac) equilibrium state. We illustrate the approach to equilibrium by numerical simulations in the isotropic three-dimensional setting.