Abstract

Spatial separation of water dimer from water monomer and larger water-clusters through the electric deflector is presented. A beam of water dimer with 93 %93~\% purity and a rotational temperature of 1.5 1.5~K was obtained. Following strong-field ionization using a 35 35~fs laser pulse with a wavelength centered around 800 800~nm and a peak intensity of 1014 W/cm210^{14}~\text{W}/\text{cm}^2 we observed proton transfer and 46 %46~\% of the ionized water dimer broke apart into a hydronium ion H3O+\text{H}_3\text{O}^+ and neutral OH.

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