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Possible "Magnéli" phases and self-alloying in the superconducting sulfur hydride

We theoretically give an infinite number of metastable crystal structures for the superconducting sulfur hydride H$_{x}$S under pressure. It has been thought that theoretically predicted structures of H$_{2}$S and H$_{3}$S exhibit low and high $T_{\rm c}$ in the experiment, respectively. The newly found structures are long-period modulated crystals where slab-like H$_{2}$S and H$_{3}$S regions intergrow in a microscopic scale. The extremely small formation enthalpy for the H$_{2}$S--H$_{3}$S boundary indicated with the first-principles calculations suggests possible alloying of these phases through formation of local H$_{3}$S regions. The modulated structures and gradual alloying transformations between them not only explain the peculiar pressure dependence of $T_{\rm c}$ in sulfur hydride observed experimentally, but also could prevail in the experimental samples under various compression schemes.