Phase Space Cell in Nonextensive Classical Systems

preprint2003arXivOpen access

Abstract

We calculate the phase space volume ΩΩ occupied by a nonextensive system of NN classical particles described by an equilibrium (or steady-state, or long-term stationary state of a nonequilibrium system) distribution function, which slightly deviates from Maxwell-Boltzmann (MB) distribution in the high energy tail. We explicitly require that the number of accessible microstates does not change respect to the extensive MB case. We also derive, within a classical scheme, an analytical expression of the elementary cell that can be seen as a macrocell, different from the third power of Planck constant. Thermodynamic quantities like entropy, chemical potential and free energy of a classical ideal gas, depending on elementary cell, are evaluated. Considering the fractional deviation from MB distribution we can deduce a physical meaning of the nonextensive parameter qq of the Tsallis nonextensive thermostatistics in terms of particle correlation functions (valid at least in the case, discussed in this work, of small deviations from MB standard case). pacs: 05.20.-y, 05.70.-a keywords: Classical Statistical Mechanics, Thermodynamics

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