Parity oscillations of Kondo temperature in a single molecule break junction

preprint2012arXivOpen access

Abstract

We study the Kondo temperature (TKT_K) of a single molecule break junction. By employing a numerical renormalization group calculations we have found that TKT_K depends dramatically upon the position of the molecule in the wire formed between the contacts. We show that TKT_K exhibits strong \emph{oscillations} when the parity of the left {and/or} right number of atomic sites (NL,NRN_L,N_R) is changed. For a given set of parameters, the maximum value of TKT_K occurs for (odd,oddodd,odd) combination, while its minimum values is observed for (even,eveneven,even). These oscillations are fully understood in terms of the effective hybridization function.

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