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Overlap of electron shells in $β$ and double-$β$ decays

The $β$ and double-$β$ decay channels, which are not accompanied by excitation of the electron shells, are suppressed due to the nonorthogonality of the electron wave functions of the parent and daughter atoms. The effect is sensitive to the contribution of the outer electron shells. Since valence electrons participate in chemical bonding and collectivize in metals, the decay rates of the unstable nuclides are modified when they are embedded in a host material. Core electrons are less affected by the environment, and their overlap amplitudes are more stable. The suppression effect is estimated for $ β^- $ decay of $^{87}$Kr, electron capture in $^{163}$Ho, and $2β^-$ decays of $^{76}$Ge, $^{100}$Mo, $^{130}$Te, and $^{136}$Xe. The overlap amplitude of the electron shells enters the relationship between the half-life of neutrinoless $2β$ decay and the effective electron neutrino Majorana mass.