On accurate computations of slowly convergent atomic properties in few-electron ions and electron-electron correlations

preprint2016arXivOpen access

Abstract

We discuss an approach to accurate numerical computations of slowly convergent properties in two-electron atoms/ions which include the negatively charged Ps−^{-} (e−e+e−e^{-} e^{+} e^{-}) and H−^{-} ions, He atom and positively charged, helium-like ions from Li+^{+} to Ni26+^{26+}. All these ions are considered in their ground 11S−1^{1}S-state(s). The slowly convergent properties selected in this study include the electron-nulceus ⟨reN2k⟩\langle r^{2 k}_{eN} \rangle and electron-electron ⟨ree2k⟩\langle r^{2 k}_{ee} \rangle expectation values for kk = 2, 3, 4 and 5.

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