Abstract
Using \emph{Spitzer} Infrared Spectrograph observations of G0--M4 III stars behind dark clouds, I construct m empirical extinction curves for , which is equivalent to between 3 and 50. For the curve appears similar to the \citet{mathis90} diffuse interstellar medium extinction curve, but with a greater degree of extinction. For , the curve exhibits lower contrast between the silicate and absorption continuum, developes ice absorption, and lies closer to the \citet{wd01} case B curve, a result which is consistent with that of \citet{flaherty07} and \citet{chiar07}. Recently work using \emph{Spitzer} Infrared Array Camera data by \citet{chapman08} independently reaches a similar conclusion, that the shape of the extinction curve changes as a function of increasing . By calculating the optical depths of the m silicate and 6.0, 6.8, and 15.2 m ice features, I determine that a process involving ice is responsible for the changing shape of the extinction curve and speculate that this process is coagulation of ice-mantled grains rather than ice-mantled grains alone.
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