Nucleation model for the description of glass formation

preprint1998arXivOpen access

Abstract

We present in this letter a model of glass formation using energy barriers and a crystal nucleation process. We then analyze the corresponding dynamical equation in the vicinity of the stationary solutions. The occurence of a pure amorphous solution (i.e. glass) is due to the contribution of a ratio ΛΛ depending on the cooling rate and the crystal nucleation frequency. We also construct time-temperature-transformation (TTT) curves in order to relate the model with the kinetic treatment of glass formation.

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