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Non-linear optical effects and third-harmonic generation in superconductors: Cooper-pairs vs Higgs mode contribution

The recent observation of a transmitted Thz pulse oscillating at three times the frequency of the incident light paves the way to a new protocol to access resonant excitations in a superconductor. Here we show that this non-linear optical process is dominated by light-induced excitation of Cooper pairs, in analogy with a standard Raman experiment. The collective amplitude (Higgs) fluctuations of the superconducting order parameter give in general a smaller contribution, unless one designs the experiment by combining properly the light polarization with the lattice symmetry.