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Maximizing the hyperpolarizability poorly determines the potential

We have optimized the zero frequency first hyperpolarizability βof a one-dimensional piecewise linear potential well containing a single electron by adjusting the shape of that potential. With increasing numbers of parameters in the potential, the maximized hyperpolarizability converges quickly to 0.708951 of the proven upper bound. The Hessian of βat the maximum has in each case only two large eigenvalues; the other eigenvalues diminish seemingly exponentially quickly, demonstrating a very wide range of nearby nearly optimal potentials, and that there are only two important parameters for optimizing β. The shape of the optimized wavefunctions converges with more parameters while the associated potentials remain substantially different, suggesting that the ground state wavefunction provides a superior physical description to the potential for the conditions that optimize the hyperpolarizability. Prospects for characterizing the two important parameters for near-optimum potentials are discussed.