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Massive star formation in Wolf-Rayet galaxies. IV: Colours, chemical composition analysis and metallicity-luminosity relations

(Abridged) We performed a multiwavelength analysis of a sample of starburst galaxies that show the presence of a substantial population of very young massive (WR) stars. Here we present the global analysis of the derived photometric and chemical properties. We compare optical/NIR colours and the physical properties (reddening coefficient, equivalent widths of the emission and underlying absorption lines, ionization degree, electron density, and electron temperature) and chemical properties with previous observations and galaxy evolution models. Attending to their absolute B-magnitude many of them are not dwarf galaxies, but they should be during their quiescent phase. We found that both C(Hb) and Wabs increase with increasing metallicity. We detected a high N/O ratio in objects showing strong WR features. The ejecta of the WR stars may be the origin of the N enrichment in these galaxies. We compared the abundances provided by the direct method with those obtained using empirical calibrations, finding that (i) the Pilyugin method is the best suitable empirical calibration, (ii) the relations between the oxygen abundance and the N2 or the O3N2 parameters provided by Pettini & Pagel (2004) give acceptable results for objects with 12+log(O/H)>8.0, and (iii) the results provided by empirical calibrations based on photoionization models are systematically 0.2-0.3 dex higher than the values derived from the direct method. The O and N abundances and the N/O ratios are related to the optical/NIR luminosity; the dispersion is consequence of the differences in the star-formation histories. Galaxies with redder colours tend to have higher oxygen and nitrogen abundances. Our detailed analysis is fundamental to understand the nature of galaxies showing strong starbursts, as well as to know their star formation history and the relationships with the environment.