Magnetization and transport properties in the superconducting Pr2_{2}Ba4_{4}Cu7_{7}O15−δ_{15-δ} with metallic double-chain

preprint2012arXivOpen access

Abstract

We have reported the effect of pressure on the magnetization, and transport properties in the nominal composition Pr2_{2}Ba4_{4}Cu7_{7}O15−δ_{15-δ} synthesized by a sol-gel technique. A reduction treatment of the as-sintered sample in vacuum causes higher superconductivity achieving Tc,on=∼30T_{c,on}=\sim 30 K for δ=0.94δ=0.94. Application of hydrostatic pressure on the oxygen depleted sample enhances its onset temperature up to 36 K at 1.2 GPa, indicating the nearly optimum doping level of the charge carrier in comparison to the pressure dependence of lower TcT_{c} samples with δ=0.45δ=0.45. Seebeck coefficient of the superconducting sample shows a metallic conduction, followed by a clear drop below Tc,onT_{c,on} and is in its temperature dependence below 100 K quite different from that of the non-superconducting one. This finding strongly suggests a dramatic change of the electronic state along the CuO double chain due to the reduction treatment for the appearance of superconductivity .

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