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Magnetization and transport properties in the superconducting Pr$_{2}$Ba$_{4}$Cu$_{7}$O$_{15-δ}$ with metallic double-chain

We have reported the effect of pressure on the magnetization, and transport properties in the nominal composition Pr$_{2}$Ba$_{4}$Cu$_{7}$O$_{15-δ}$ synthesized by a sol-gel technique. A reduction treatment of the as-sintered sample in vacuum causes higher superconductivity achieving $T_{c,on}=\sim 30$ K for $δ=0.94$. Application of hydrostatic pressure on the oxygen depleted sample enhances its onset temperature up to 36 K at 1.2 GPa, indicating the nearly optimum doping level of the charge carrier in comparison to the pressure dependence of lower $T_{c}$ samples with $δ=0.45$. Seebeck coefficient of the superconducting sample shows a metallic conduction, followed by a clear drop below $T_{c,on}$ and is in its temperature dependence below 100 K quite different from that of the non-superconducting one. This finding strongly suggests a dramatic change of the electronic state along the CuO double chain due to the reduction treatment for the appearance of superconductivity .

preprint2012arXivOpen access

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