Lattice distortion in TmCo2_2: a poly- and single- crystal study

preprint2020arXivOpen access

Abstract

Within the RCo2_2 family of compounds, a structural distortion linked with the onset of magnetic ordering around the critical temperature can be observed. One of the less explored RCo2_2 compounds is TmCo2_2 probably due to its low Curie temperature. Exceptionally this compound, given its position at the end of the ferrimagnetic series, shows discrepancies in the ordering of the Co sub-lattice because of a weak Weiss molecular field. In this paper we focus on the structural distortion in TmCo2_2, which appears together with the magnetic ordering around the critical temperature of TC∼3.6T_{C}\sim3.6~K. Poly-crystals as well as single-crystals of TmCo2_2 were used in our experiments. For both kinds of samples we observed the same type of the rhombohedral distortion along the [111] direction from the cubic Fd3ˉ\bar{3}m to R3ˉ\bar{3}m space group. The relation between observed magnetic and structural properties in this compound is discussed.

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