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Intertwined atomic-nanoscale-microscale structures via intralayer anisotropic Fe-chains in the layered ferromagnet FePd2Te2

Controlling mesoscale and nanoscale material structures and properties through self-organized atomic behavior is essential for atomic-scale manufacturing. However, direct and visual studies on the cross-scale effects of such atomic self-organization on mesoscopic structures remain scarce. Here, we report the intertwined atomic-nanoscale-mesoscale structures via the intralayer Fe-chains in the sandwich-like layered FePd2Te2 crystal by scanning tunneling microscopy (STM) and atomic force microscopy (AFM). The hierarchical orthogonal corrugated morphologies are directly revealed and attributed to its chain-orientation-determined twinning-domain effect. Both Fe-chains of middle-sublayer and two kinds of Te atoms of top-sublayer are further atomically resolved at the sub-Å level, indicating the critical effects of Pd-atoms/voids on the intra-layer anisotropic Fe-chains and the interlayer structural alignment. The thermal-induced and strain-related structural transitions of surface layer are further investigated and discussed based on the proposed filling model of Pd-voids by the intralayer Pd-atoms. Our work not only provides deep understanding of this exotic layered magnetic material, and will inspire more perspectives for tailoring its anisotropic atomic-to-mesoscale structures and properties.