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Internal structure of nanoparticles of Al generated by laser ablation in liquid ethanol

Al NPs are synthesized by laser ablation of a bulk Al target immersed into liquid ethanol saturated with hydrogen at atmospheric pressure. The nanoparticles possess a well-distinguished core-shell structure. High Resolution Transmission Electron Microscopy shows several layers inside the Al nanoparticle: oxide layer, amorphous Al, single crystal Al, and a cavity in the center. Formation of the cavity is attributed to the sharp increase of hydrogen dissolution in Al upon its melting and its eventual release after the solidification.

preprint2010arXivOpen access
G. ViauV. ColliereG. A. Shafeev
cond-mat.mes-hallcond-mat.mtrl-sci
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G. ViauV. ColliereG. A. Shafeev

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