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How instanton combinatorics solves Painlevé VI, V and III's

We elaborate on a recently conjectured relation of Painlevé transcendents and 2D CFT. General solutions of Painlevé VI, V and III are expressed in terms of $c=1$ conformal blocks and their irregular limits, AGT-related to instanton partition functions in $\mathcal{N}=2$ supersymmetric gauge theories with $N_f=0,1,2,3,4$. Resulting combinatorial series representations of Painlevé functions provide an efficient tool for their numerical computation at finite values of the argument. The series involve sums over bipartitions which in the simplest cases coincide with Gessel expansions of certain Toeplitz determinants. Considered applications include Fredholm determinants of classical integrable kernels, scaled gap probability in the bulk of the GUE, and all-order conformal perturbation theory expansions of correlation functions in the sine-Gordon field theory at the free-fermion point.