Highly Efficient Fuel Cell Electrodes from Few-Layer Graphene Sheets and Electrochemically Deposited Palladium Nanoparticles

An extremely efficient ethanol fuel cell electrode is produced by combining the large surface area of vertically oriented and highly conductive few-layer graphene sheets with electrochemically deposited palladium nanoparticles. The electrodes show an extraordinary high catalyst activity of up to 7977 mA/(mg Pd) at low catalyst loadings of 0.64 $μ$g/cm$^2$ and a very high current density of up to 106 mA/cm$^2$ at high catalyst loadings of 83 $μ$g/cm$^2$. Moreover, the low onset potentials combined with a good poisoning resistance and long-term stability make these electrodes highly suitable for real applications. These features are achieved by using a newly developed electrochemical catalyst deposition process exploiting high voltages of up to 3.5 kV. This technique allows controlling the catalyst amount ranging from a homogeneous widespread distribution of small ($\leq$ 10 nm) palladium nanoparticles to rather dense layers of particles, while every catalyst particle has electrical contact to the graphene electrode.

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