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High resolution spectroscopy of ultracool M dwarfs

(abridged) We present high-resolution echelle spectroscopy of a photometricaly-selected sample if thirty-nine dwarfs with spectral types between M6.5 and L0.5. Two stars, 2MASSI 0253202+271333 and 2MASSW 0952219-192431, are double-lined spectroscopic binaries. We have used our observations to search for Li I 6708 A absorption, characteristic of sub-stellar mass; estimate the level of chromospheric activity through measurement of H-alpha emission fluxes; measure rotational velocities via line broadening; and determine radial velocities and Galactic space motions. Two dwarfs have strong lithium absorption, the previously-known brown dwarf, LP 944-20, and 2MASSI J0335020+234235, which we identify as a probable 0.06 M_sun brown dwarf, age ~1 Gyr. We have investigated the prospect of using the observed frequency of lithium absorption amongst ultracool M dwarfs (M7 to M9.5) as a probe of the initial mass function. The available observations are difficult to reconcile with Salpeter-like power-law mass functions (alpha > 2) for masses below 0.1M_Sun. A comparison between the rotational velocities and -alpha fluxes shows no evidence for significant correlation. Velocity dispersions are significantly lower than those measured for nearby M dwarfs, but show remarkable similarity to results for earlier-type emission-line (dMe) dwarfs. The latter are generally assigned ages of less than ~3 Gyrs.