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High Metallicity and Non-equilibrium Chemistry in the Dayside Atmosphere of hot-Neptune GJ 436b

We present a detailed analysis of the dayside atmosphere of the hot-Neptune GJ~436b, based on recent Spitzer observations. We report statistical constraints on the thermal and chemical properties of the planetary atmosphere, study correlations between the various molecular species, and discuss scenarios of equilibrium and non-equilibrium chemistry in GJ 436b. We model the atmosphere with a one-dimensional line-by-line radiative transfer code with parameterized molecular abundances and temperature structure. We explore the model parameter space with 10^6 models, using a Markov chain Monte Carlo scheme. Our results encompass previous findings, indicating a paucity of methane, an overabundance of CO and CO2, and a slight underabundance of H2O, as compared to equilibrium chemistry with solar metallicity. The concentrations of the species are highly correlated. Our best-fit, and most plausible, constraints require a CH4 mixing ratio of 1.0E-7 to 1.0E-6, with CO >= 1.0E-3, CO2 ~ 1.0E-6 to 1.0E-4, and H2O <= 1.0E-4; higher CH4 would require much higher CO and CO2. Based on calculations of equilibrium and non-equilibrium chemistry, we find that the observed abundances can potentially be explained by a combination of high metallicity (~ 10 x solar) and vertical mixing with Kzz ~ 10^6 - 10^7 cm^2/s. The inferred metallicity is enhanced over that of the host star which is known to be consistent with solar metallicity. Our constraints rule out a dayside thermal inversion in GJ 436b. We emphasize that the constraints reported in this work depend crucially on the observations in the two Spitzer channels at 3.6 micron and 4.5 micron. Future observations with warm Spitzer and with the James Webb Space Telescope will be extremely important to improve upon the present constraints on the abundances of carbon species in the dayside atmosphere of GJ 436b.