Ground state of many-electron systems based on the action function

preprint2020arXivOpen access

Abstract

The Hilbert space for an interacting electron system increases exponentially with electron number NN. This limits the concept of wavefunctions ψψ based on solutions of the Schrödinger equation to N≤N0N \leq N_0 with N0≃103N_0 \simeq 10^3 \cite{Kohn1999}. It is argued that this exponential wall problem (EWP) is connected with an increasing redundance of information contained, e.g., in the ground-state of the system and it's wavefunction. The EWP as well as redundance of information are avoided when the characterization of the ground state is based on the action function RR rather than on the solutions ψψ of the Schödinger equation. Both are related through a logarithm, i.e., R=−iℏ lnψR = -i \hbar \ ln ψ. Working with the logarithm is made possible by the use of cumulants. It is pointed out the way electronic structure calculations for periodic solids may use this concept.

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