Gauge- and coordinate-invariant equations for two-component systems

preprint2022arXivOpen access

Abstract

The Schrödinger-like equations for the marginal and conditional probability amplitudes resulting from the exact factorization of the wavefunction of a two-component system are derived in a form that is invariant to gauge and coordinate transformations. Coupled equations equivalent to the nonrelativistic Schrödinger equation of a molecule are derived as an example.

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