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Fourier law, phase transitions and the stationary Stefan problem

We study the one-dimensional stationary solutions of an integro-differential equation derived by Giacomin and Lebowitz from Kawasaki dynamics in Ising systems with Kac potentials, \cite{GiacominLebowitz}. We construct stationary solutions with non zero current and prove the validity of the Fourier law in the thermodynamic limit showing that below the critical temperature the limit equilibrium profile has a discontinuity (which defines the position of the interface) and satisfies a stationary free boundary Stefan problem. Under-cooling and over-heating effects are also studied. We show that if metastable values are imposed at the boundaries then the mesoscopic stationary profile is no longer monotone and therefore the Fourier law is not satisfied. It regains however its validity in the thermodynamic limit where the limit profile is again monotone away from the interface.

preprint2010arXivOpen access

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