Flexible control of the Peierls transition in metallic C60_{60} polymers

preprint2011arXivOpen access

Abstract

The metal-semiconductor transition of peanut-shaped fullerene (C60_{60}) polymers is clarified by considering the electron-phonon coupling in the uneven structure of the polymers. We established a theory that accounts for the transition temperature TcT_c reported in a recent experiment and also suggests that TcT_c is considerably lowered by electron doping or prolonged irradiation during synthesis. The decrease in TcT_c is an appealing phenomenon with regard to realizing high-conductivity C60_{60}-based nanowires even at low temperatures.

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