Extended space charge near non-ideally selective membranes and nanochannels

We demonstrate the role of selectivity variation in the structure of the non-equilibrium extended space-charge using 1D analytic and 2D numerical Poisson-Nernst-Planck models for the electro- diffusive transport of a symmetric electrolyte. This provides a deeper understanding of the underly- ing mechanism behind a previously-observed maximum in the resistance-voltage curve for a shallow micro-nanochannel interface device [Schiffbauer, Liel, Leibowitz, Park, and Yossifon, submitted to Phys. Rev. E.]. The current study helps to establish a connection between parameters such as the geometry and nanochannel surface-charge and the control of selectivity and resistance in the over-limiting current regime.

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