Abstract
Discrimination between unknown processes chosen from a finite set is experimentally shown to be possible even in the case of non-orthogonal processes. We demonstrate unambiguous deterministic quantum process discrimination (QPD) of non-orthogonal processes using properties of entanglement, additional known unitaries, or higher dimensional systems. Single qubit measurement and unitary processes and multipartite unitaries (where the unitary acts non-separably across two distant locations) acting on photons are discriminated with a confidence of in all cases.
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