Paper detail

Experimental observation of triple correlations in fluids

We present arguments for the hypothesis that under some conditions, triple correlations of density fluctuations in fluids can be detected experimentally by the method of molecular spectroscopy. These correlations manifest themselves in the form of the so-called 1.5- (i.e., sesquialteral) scattering. The latter is of most significance in the pre-asymptotic vicinity of the critical point and can be registered along certain thermodynamic paths. Its presence in the overall scattering pattern is demonstrated by our processing experimental data for the depolarization factor. Some consequences of these results are discussed.