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Exoplanet characterization with NASA's Habitable Worlds Observatory

Exoplanet atmosphere characterization has seen revolutionary advances over the last few years, providing us with unique insights into atmospheric chemistry, dynamics and planet formation mechanisms. However, true solar system analog planets remain inaccessible. A major goal for exoplanet science over the coming decades is to observe, and characterize, temperate rocky planets and cool gas giants in orbit around solar-type stars, with the prospect of detecting signs of habitability or even life. Characterization and categorization of these planets relies on direct spectroscopic observations capable of identifying molecular species in their atmospheres; however, these observations represent a substantial engineering challenge due to the extreme contrast between a temperate, Earth-sized exoplanet and its parent star. NASA's next flagship mission, the Habitable Worlds Observatory (HWO) - planned for launch in the mid-2040s - will boast a coronagraphic instrument capable of reaching the needed 10$^{-10}$ contrast, on an ultrastable platform enabling long integration times to achieve the required signal to noise. HWO will cover near-ultraviolet to the near-infrared wavelengths, enabling detections of key biosignature molecules and habitability indicators such as ocean glint and a vegetation `red edge'. Via early involvement in this groundbreaking observatory, including a potential UK instrument contribution, the UK exoplanet community now has an important opportunity to influence the telescope's design. To maintain our international competitiveness, we must be at the forefront of observational campaigns with HWO when it eventually launches, and this comes with the need for parallel development in laboratory astrophysics and computational modelling. Maximising our exploitation of this transformative NASA mission requires consistent financial support in these areas across the next two decades.