Existence of Minimizers in Restricted Hartree-Fock Theory

preprint2012arXivOpen access

Abstract

In this note we establish the existence of ground states for atoms within several restricted Hartree-Fock theories. It is shown, for example, that there exists a ground state for closed shell atoms with NN electrons and nuclear charge Z≥N−1Z \geq N-1. This has to be compared with the general Hartree-Fock theory where the existence of a minimizer is known for Z>N−1Z>N-1 only.

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