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Paper detail

Exciton properties of selected aromatic hydrocarbon systems

We have examined the singlet excitons in two representatives of acene-type (tetracene and pentacene) and phenacene-type (chrysene and picene) molecular crystals, respectively, using electron energy-loss spectroscopy at low temperatures. We show that the excitation spectra of the two hydrocarbon families significantly differ. Moreover, close inspection of the data indicates that there is an increasing importance of charge-transfer excitons at lowest excitation energy with increasing length of the molecules.

preprint2013arXivOpen access
Friedrich RothBenjamin MahnsSilke HampelMarkus NohrHelmuth BergerBernd BüchnerMartin Knupfer
cond-mat.mtrl-sci
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Friedrich RothBenjamin MahnsSilke HampelMarkus NohrHelmuth BergerBernd BüchnerMartin Knupfer

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